Metal Promoted Diels-Alder Reactions

Florian Gallier (1, 2)

1 BioCIS - Biomolécules : Conception, Isolement, Synthèse
2 LCB - Laboratoire de Chimie Biologique

The Diels-Alder cycloaddition between a (hetero)diene and a (hetero)dienophile can be performed with metal Lewis Acids. Such activation often increases the rate of the reaction and has an influence on the observed selectivity. The most recent advances on metal promoted Diels-Alder reactions are reviewed.

Mots clés: Diels-Alder reaction; Catalysis; Selectivity; Asymmetric synthesis; Diels-Alder reaction

Domaines: Chimie organique; Catalyse

Florian Gallier. Metal Promoted Diels-Alder Reactions. Current Organic Chemistry, 2016, 20 (21), pp.2222-2253. ⟨10.2174/1385272820666160610094502⟩. ⟨hal-03548863⟩